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By Daniel Wegener, Fachbereich Biologie, Alberto Pérez-Bitrián, Niklas Limberg| Wiley Online Library Verified Introduction Boron-based Lewis acids offer a plethora of applications in organic and organometallic chemistry.1 One of the most prominent examples of a boron-based Lewis acid is tris(pentafluorophenyl)borane (B(C6F5)3, ‘BCF’), which combines a high Lewis acidity with a high steric demand.2 Among its applications, it is a well-known activator of metallocene-based polymerization catalysts, as well as a popular catalyst in organic synthesis.3 Moreover, its high steric demand has made it...
By Daniel Wegener, Fachbereich Biologie, Freie Universität Berlin, Kurt Hoffmann| Royal Society of Chemistry Verified Air-stable aryl derivatives of pentafluoroorthotellurate† DanielWegener, a Kurt F. Hoffmann, a AlbertoPérez-Bitrián, a IlaydaBayindir,a Amiera N. Hadi,a AnjaWiesnera and SebastianRiedel *a Abstract We report on two different sets of air-stable derivatives of pentafluoroorthotellurate containing fluorinated and non-fluorinated aryl groups.
By Daniel Wegener, Fachbereich Biologie, Alberto Pérez-Bitrián, Niklas Limberg| Wiley Online Library Verified Introduction Boron-based Lewis acids offer a plethora of applications in organic and organometallic chemistry.1 One of the most prominent examples of a boron-based Lewis acid is tris(pentafluorophenyl)borane (B(C6F5)3, ‘BCF’), which combines a high Lewis acidity with a high steric demand.2 Among its applications, it is a well-known activator of metallocene-based polymerization catalysts, as well as a popular catalyst in organic synthesis.3 Moreover, its high steric demand has made it...
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