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Head of Party, Groupe Barrière
New York
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Mechanistic and Electronic Insights into a Working NiAu Single-Atom Alloy Ethanol Dehydrogenation Catalyst
By Georgios Giannakakis, Paul Kress, Kaining Duanmu, Hio Tong Ngan| ACS Publications@ Elucidation of reaction mechanisms and the geometric and electronic structure of the active sites themselves is a challenging, yet essential task in the design of new heterogeneous catalysts. Such investigations are best implemented via a multipronged approach that comprises ambient pressure catalysis, surface science, and theory.
By Matthew Uhlman, Romain Reocreux, Theodore Thuening, Paul Kress| Royal Society of Chemistry Verified Efficient and Selective Carbon-Carbon Coupling on Coke-Resistant PdAu Single-Atom Alloys We demonstrate that PdAu single-atom alloy model catalysts offer a heterogeneous route to selective Würtz-type C-C coupling. Specifically, when methyl iodide is exposed to an otherwise unreactive Au(111) surface, single Pd atoms in the surface layer promote C-I dissociation and C-C coupling, leading to the selective formation of ethane.
Mechanistic and Electronic Insights into a Working NiAu Single-Atom Alloy Ethanol Dehydrogenation Catalyst
By Georgios Giannakakis, Paul Kress, Kaining Duanmu, Hio Tong Ngan| ACS Publications@ Elucidation of reaction mechanisms and the geometric and electronic structure of the active sites themselves is a challenging, yet essential task in the design of new heterogeneous catalysts. Such investigations are best implemented via a multipronged approach that comprises ambient pressure catalysis, surface science, and theory.